HIGH-FIELD DNP / EPR LABORATORY
Our Publications
2024
Nir-Arad, O.; Shlomi, D. H.; Israelstam, A.; Amit, T.; Manukovsky, N.; Fialkov, A. B.; Kaminker, I. The CW-EPR Capabilities of a Dual DNP/EPR Spectrometer Operating at 14 and 7 T. Journal of Magnetic Resonance 2024, 360, 107635.
2023
Nir-Arad, O.; Shlomi, D. H.; Manukovsky, N.; Laster, E.; Kaminker, I. Nitrogen Substitutions Aggregation and Clustering in Diamonds as Revealed by High-Field Electron Paramagnetic Resonance. J. Am. Chem. Soc. 2023. (In press)
Ma, J.; Das, J.; Zhang, J.; Cheng, J.; Sorcar, S.; Rosen, B. A.; Shekhter, P.; Dobrovetsky, R.; Flaxer, E.; Yavor, Y.; Shen, R.; Kaminker, I.; Goldbourt, A.; Gozin, M. Carbon-Nitride Popcorn—A Novel Catalyst Prepared by Self-Propagating Combustion of Nitrogen-Rich Triazenes. Small 2023, 19 (12), 2205994.
2022
Petrutik, N.; Kaminker, I.; Flaxer, E.; Shem-Tov, D.; Giladi, T.; Bar-Bechor, Y.; Das, J.; Gozin, M. Janus-Type Hypergolic Fuels for Hybrid Systems Using Hydrogen Peroxide and Hydroxylammonium Nitrate-Based Oxidizers. Chemical Engineering Journal 2023, 454, 140170.
2021
Shimon, D.; Kaminker, I. A Transition from Solid Effect to Indirect Cross Effect with Broadband Microwave Irradiation. Physical Chemistry Chemical Physics 2022, 24 (12), 7311–7322.
2020
Tzadikov, J.; Levy, N. R.; Abisdris, L.; Cohen, R.; Weitman, M.; Kaminker, I.; Goldbourt, A.; Ein-Eli, Y.; Shalom, M. Bottom-Up Synthesis of Advanced Carbonaceous Anode Materials Containing Sulfur for Na-Ion Batteries. Advanced Functional Materials 2020, 30 (19), 2000592.
2019
Tagami, K.; Equbal, A.; Kaminker, I.; Kirtman, B.; Han, S. Biradical Rotamer States Tune Electron J Coupling and MAS Dynamic Nuclear Polarization Enhancement. Solid State Nuclear Magnetic Resonance 2019, 101, 12–20.
Kaminker, I. Recent Advances in Magic Angle Spinning-Dynamic Nuclear Polarization Methodology. Israel Journal of Chemistry 2019, 59 (11–12), 990–1000.
Leavesley, A.; Kaminker, I.; Han, S. Versatile Dynamic Nuclear Polarization Hardware with Integrated Electron Paramagnetic Resonance Capabilities. In eMagRes; John Wiley & Sons, Ltd, 2018; pp 133–154.
2018
Kaminker, I.; Han, S. Amplification of Dynamic Nuclear Polarization at 200 GHz by Arbitrary Pulse Shaping of the Electron Spin Saturation Profile. J. Phys. Chem. Lett. 2018, 9 (11), 3110–3115.
Kaminker, R.; Kaminker, I.; Gutekunst, W. R.; Luo, Y.; Lee, S.; Niu, J.; Han, S.; Hawker, C. J. Tuning Conformation and Properties of Peptidomimetic Backbones through Dual N/Cα-Substitution. Chem. Commun. 2018, 54 (41), 5237–5240.
Jain, S. K.; Siaw, T. A.; Equbal, A.; Wilson, C. B.; Kaminker, I.; Han, S. Reversal of Paramagnetic Effects by Electron Spin Saturation. J. Phys. Chem. C 2018, 122 (10), 5578–5589.
Leavesley, A.; Jain, S.; Kamniker, I.; Zhang, H.; Rajca, S.; Rajca, A.; Han, S. Maximizing NMR Signal per Unit Time by Facilitating the e–e–n Cross Effect DNP Rate. Phys. Chem. Chem. Phys. 2018, 20 (43), 27646–27657.
2017
Kaminker, I.; Wei, W.; Schrader, A. M.; Talmon, Y.; Valentine, M. T.; Israelachvili, J. N.; Waite, J. H.; Han, S. Simple Peptide Coacervates Adapted for Rapid Pressure-Sensitive Wet Adhesion. Soft Matter 2017, 13 (48), 9122–9131.
Kaminker, I.; Barnes, R.; Han, S. Arbitrary Waveform Modulated Pulse EPR at 200GHz. Journal of Magnetic Resonance 2017, 279, 81–90.
Ramirez Cohen, M.; Mendelman, N.; Radoul, M.; Wilson, T. D.; Savelieff, M. G.; Zimmermann, H.; Kaminker, I.; Feintuch, A.; Lu, Y.; Goldfarb, D. Thiolate Spin Population of Type I Copper in Azurin Derived from 33S Hyperfine Coupling. Inorg. Chem. 2017, 56 (11), 6163–6174.
Leavesley, A.; Shimon, D.; Siaw, T. A.; Feintuch, A.; Goldfarb, D.; Vega, S.; Kaminker, I.; Han, S. Effect of Electron Spectral Diffusion on Static Dynamic Nuclear Polarization at 7 Tesla. Phys. Chem. Chem. Phys. 2017, 19 (5), 3596–3605.
2016
Siaw, T. A.; Leavesley, A.; Lund, A.; Kaminker, I.; Han, S. A Versatile and Modular Quasi Optics-Based 200GHz Dual Dynamic Nuclear Polarization and Electron Paramagnetic Resonance Instrument. J Magn Reson 2016, 264, 131–153.
Kaminker, I.; Shimon, D.; Hovav, Y.; Feintuch, A.; Vega, S. Heteronuclear DNP of Protons and Deuterons with TEMPOL. Phys. Chem. Chem. Phys. 2016, 18 (16), 11017–11041.
2015
Shimon, D.; Hovav, Y.; Kaminker, I.; Feintuch, A.; Goldfarb, D.; Vega, S. Simultaneous DNP Enhancements of 1H and 13C Nuclei: Theory and Experiments. Phys. Chem. Chem. Phys. 2015, 17 (17), 11868–11883.
Hovav, Y.; Shimon, D.; Kaminker, I.; Feintuch, A.; Goldfarb, D.; Vega, S. Effects of the Electron Polarization on Dynamic Nuclear Polarization in Solids. Phys. Chem. Chem. Phys. 2015, 17 (8), 6053–6065.
Hovav, Y.; Kaminker, I.; Shimon, D.; Feintuch, A.; Goldfarb, D.; Vega, S. The Electron Depolarization during Dynamic Nuclear Polarization: Measurements and Simulations. Phys. Chem. Chem. Phys. 2014, 17 (1), 226–244.
Kaminker, I.; Bye, M.; Mendelman, N.; Gislason, K.; Sigurdsson, S. T.; Goldfarb, D. Distance Measurements between Manganese(II) and Nitroxide Spin-Labels by DEER Determine a Binding Site of Mn2+ in the HP92 Loop of Ribosomal RNA. Phys. Chem. Chem. Phys. 2015, 17 (23), 15098–15102.
2014
Kaminker, I.; Wilson, T. D.; Savelieff, M. G.; Hovav, Y.; Zimmermann, H.; Lu, Y.; Goldfarb, D. Correlating Nuclear Frequencies by Two-Dimensional ELDOR-Detected NMR Spectroscopy. J Magn Reson 2014, 240, 77–89.
Rizzato, R.; Kaminker, I.; Vega, S.; Bennati, M. Cross-Polarisation Edited ENDOR. Molecular Physics 2013, 111 (18–19), 2809–2823.
Edwards, D. T.; Huber, T.; Hussain, S.; Stone, K. M.; Kinnebrew, M.; Kaminker, I.; Matalon, E.; Sherwin, M. S.; Goldfarb, D.; Han, S. Determining the Oligomeric Structure of Proteorhodopsin by Gd3+-Based Pulsed Dipolar Spectroscopy of Multiple Distances. Structure 2014, 22 (11), 1677–1686.
2013
Mentink-Vigier, F.; Collauto, A.; Feintuch, A.; Kaminker, I.; Tarle, V.; Goldfarb, D. Increasing Sensitivity of Pulse EPR Experiments Using Echo Train Detection Schemes. Journal of Magnetic Resonance 2013, 236, 117–125.
Raitsimring, A.; Astashkin, A. V.; Enemark, J. H.; Kaminker, I.; Goldfarb, D.; Walter, E. D.; Song, Y.; Meade, T. J. Optimization of Pulsed DEER Measurements for Gd-Based Labels: Choice of Operational Frequencies, Pulse Durations and Positions, and Temperature. Appl Magn Reson 2013, 44 (6), 649–670.
Matalon, E.; Kaminker, I.; Zimmermann, H.; Eisenstein, M.; Shai, Y.; Goldfarb, D. Topology of the Trans-Membrane Peptide WALP23 in Model Membranes under Negative Mismatch Conditions. J. Phys. Chem. B 2013, 117 (8), 2280–2293.
Kaminker, I.; Tkach, I.; Manukovsky, N.; Huber, T.; Yagi, H.; Otting, G.; Bennati, M.; Goldfarb, D. W-Band Orientation Selective DEER Measurements on a Gd3+/Nitroxide Mixed-Labeled Protein Dimer with a Dual Mode Cavity. J Magn Reson 2013, 227, 66–71.
2012
Kaminker, I.; Yagi, H.; Huber, T.; Feintuch, A.; Otting, G.; Goldfarb, D. Spectroscopic Selection of Distance Measurements in a Protein Dimer with Mixed Nitroxide and Gd3+ Spin Labels. Phys. Chem. Chem. Phys. 2012, 14 (13), 4355–4358.
2011
Kaminker, I.; Sushenko, A.; Potapov, A.; Daube, S.; Akabayov, B.; Sagi, I.; Goldfarb, D. Probing Conformational Variations at the ATPase Site of the RNA Helicase DbpA by High-Field Electron–Nuclear Double Resonance Spectroscopy. J. Am. Chem. Soc. 2011, 133 (39), 15514–15523.
Kaminker, I.; Florent, M.; Epel, B.; Goldfarb, D. Simultaneous Acquisition of Pulse EPR Orientation Selective Spectra. Journal of Magnetic Resonance 2011, 208 (1), 95–102.
Gordon-Grossman, M.; Kaminker, I.; Gofman, Y.; Shai, Y.; Goldfarb, D. W-Band Pulse EPR Distance Measurements in Peptides Using Gd3+–Dipicolinic Acid Derivatives as Spin Labels. Phys. Chem. Chem. Phys. 2011, 13 (22), 10771–10780.
Florent, M.; Kaminker, I.; Nagarajan, V.; Goldfarb, D. Determination of the 14N Quadrupole Coupling Constant of Nitroxide Spin Probes by W-Band ELDOR-Detected NMR. J Magn Reson 2011, 210 (2), 192–199.
Feintuch, A.; Shimon, D.; Hovav, Y.; Banerjee, D.; Kaminker, I.; Lipkin, Y.; Zibzener, K.; Epel, B.; Vega, S.; Goldfarb, D. A Dynamic Nuclear Polarization Spectrometer at 95 GHz/144 MHz with EPR and NMR Excitation and Detection Capabilities. J Magn Reson 2011, 209 (2), 136–141.
2010
Kaminker, I.; Goldberg, H.; Neumann, R.; Goldfarb, D. High-Field Pulsed EPR Spectroscopy for the Speciation of the Reduced [PV2Mo10O40]6− Polyoxometalate Catalyst Used in Electron-Transfer Oxidations. Chemistry – A European Journal 2010, 16 (33), 10014–10020.
2009
Karton, A.; Kaminker, I.; Martin, J. M. L. Economical Post-CCSD(T) Computational Thermochemistry Protocol and Applications to Some Aromatic Compounds. J Phys Chem A 2009, 113 (26), 7610–7620.
Kaminker, I.; Potapov, A.; Feintuch, A.; Vega, S.; Goldfarb, D. Population Transfer for Signal Enhancement in Pulsed EPR Experiments on Half Integer High Spin Systems. Phys. Chem. Chem. Phys. 2009, 11 (31), 6799–6806.
Goldberg, H.; Kaminker, I.; Goldfarb, D.; Neumann, R. Oxidation of Carbon Monoxide Cocatalyzed by Palladium(0) and the H5PV2Mo10O40 Polyoxometalate Probed by Electron Paramagnetic Resonance and Aerobic Catalysis. Inorg.
Chem. 2009, 48 (16), 7947–7952.
2008
Goldfarb, D.; Lipkin, Y.; Potapov, A.; Gorodetsky, Y.; Epel, B.; Raitsimring, A. M.; Radoul, M.; Kaminker, I. HYSCORE and DEER with an Upgraded 95GHz Pulse EPR Spectrometer. J Magn Reson 2008, 194 (1), 8–15.